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- Title
Expanding the Perovskite Periodic Table to Include Chalcogenide Alloys with Tunable Band Gap Spanning 1.5–1.9 eV.
- Authors
Sadeghi, Ida; Van Sambeek, Jack; Simonian, Tigran; Xu, Michael; Ye, Kevin; Cai, Tao; Nicolosi, Valeria; LeBeau, James M.; Jaramillo, Rafael
- Abstract
Optoelectronic technologies are based on families of semiconductor alloys. It is rare that a new semiconductor alloy family is developed to the point where epitaxial growth is possible; since the 1950s, this has happened approximately once per decade. Herein, this work demonstrates epitaxial thin film growth of semiconducting chalcogenide perovskite alloys in the Ba‐Zr‐S‐Se system by gas‐source molecular beam epitaxy (MBE). This work stabilizes the full range y = 0 − 3 of compositions BaZrS(3‐y)Sey in the perovskite structure. The resulting films are environmentally stable and the direct band gap (Eg) varies strongly with Se content, as predicted by theory, with Eg = 1.9 − 1.5 eV for y = 0 − 3. This creates possibilities for visible and near‐infrared (VIS–NIR) optoelectronics, solid‐state lighting, and solar cells using chalcogenide perovskites.
- Subjects
BAND gaps; MOLECULAR beam epitaxy; CHALCOGENIDE glass; CHALCOGENIDES; PEROVSKITE; ALLOYS; CHEMICAL elements
- Publication
Advanced Functional Materials, 2023, Vol 33, Issue 41, p1
- ISSN
1616-301X
- Publication type
Article
- DOI
10.1002/adfm.202304575