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- Title
NMR Study of Intercalates and Grafted Organic Derivatives of H 2 La 2 Ti 3 O 10.
- Authors
Shelyapina, Marina G.; Silyukov, Oleg I.; Lushpinskaia, Irina P.; Kurnosenko, Sergey A.; Mazur, Anton S.; Shenderovich, Ilya G.; Zvereva, Irina A.; Goodilin, Eugene A.; Tarasov, Alexey
- Abstract
The protonated perovskite-like titanate H2La2Ti3O10 has been used to produce organic-inorganic hybrids with simple organic molecules: methylamine, methanol, monoethanolamine, and n-butylamine. The optimal pathways for the preparation of such hybrids are summarized. Solid-state NMR, combined with thermal analysis, Raman, and IR spectroscopy, has been applied to determine the bonding type in the obtained organic-inorganic hybrids. It has been found that, in the methanolic hybrid, the organic residues are covalently bound to the inorganic matrix. In contrast, in the methylamine and n-butylamine hybrids, the organic molecules are intercalated into the inorganic matrix in cationic forms. The structure of the monoethanolamine hybrid is composite and includes both the covalently bound and intercalated organic species.
- Subjects
ETHANOLAMINES; THERMAL analysis; TITANATES; SPECTRUM analysis
- Publication
Molecules, 2020, Vol 25, Issue 22, p5229
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules25225229