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- Title
Iodoarylation of Arylalkynes with Molecular Iodine in the Presence of Hypervalent Iodine Reagents.
- Authors
Rahman, Md. Ataur; Kitamura, Tsugio
- Abstract
Iodoarylation of arylacetylenes was performed using a simple reagent system composed of molecular iodine and [bis(benzoyloxy)iodo]benzene. Most arylacetylenes efficiently underwent the iodoarylation reaction with electron-rich arenes to give trans 1,1-diaryl-2-iodoethene adducts regio- and stereoselectively. As an exception, the iodoarylation of p-methoxyphenylacetylene resulted in a mixture of E- and Z-isomers of the corresponding product.
- Subjects
ARYLATION; ALKYNES; HYDROCARBONS; IODINE; CHEMICAL warfare agents; BENZENE; ACETYLENE; AROMATIC compounds; NUCLEAR isomers
- Publication
Molecules, 2009, Vol 14, Issue 9, p3132
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules14093132