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- Title
Tandem Chiral Cu(II) Phosphate‐Catalyzed Deoxygenation of Nitrones/Enantioselective Povarov Reaction with Enecarbamates.
- Authors
Gelis, Coralie; Levitre, Guillaume; Guérineau, Vincent; Touboul, David; Neuville, Luc; Masson, Géraldine
- Abstract
A new catalytic enantioselective tandem deoxygenation/aza‐Diels‐Alder reaction of nitrones with enecarbamates was serendipitously discovered in the presence of chiral copper(II) diphosphate complexes. This process affords a wide range of 4‐aminotetrahydroquinolines in respectable yields under mild conditions with good to excellent ee values.
- Subjects
NITRONES; NITROALDOL reactions; DEOXYGENATION; COPPER; HETEROCYCLIC compounds; AZA compounds
- Publication
European Journal of Organic Chemistry, 2019, Vol 2019, Issue 31/32, p5151
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201900547