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- Title
Synthesis of Trifluoroacetyl-Substituted Cyclopropanes Using Onium Ylides.
- Authors
Winter, Michael; Gaunersdorfer, Christina; Roiser, Lukas; Zielke, Katharina; Monkowius, Uwe; Waser, Mario
- Abstract
The use of carbonyl-stabilized ammonium- and sulfonium ylides allows for the synthesis of highly-functionalized trifluoroacetyl-substituted cyclopropanes. It turned out that the diastereoselectivities strongly depend on the nature of the chosen ylide and the employed base. The products could be obtained in good yields under operationally simple conditions.
- Subjects
CYCLOPROPANE synthesis; AMMONIUM; CHEMICAL yield; CARBONYL compounds; SULFONIUM compounds
- Publication
European Journal of Organic Chemistry, 2018, Vol 2018, Issue 3, p418
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201701699