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- Title
Palladium-Catalyzed 3-Aryl-5-acyl-1,2,4-thiadiazole Formation from Ketones, Amidines, and Sulfur Powder.
- Authors
Wang, Zilong; Xie, Hao; Xiao, Fuhong; Guo, Yanjun; Huang, Huawen; Deng, Guo‐Jun
- Abstract
An efficient strategy for the preparation of 3,5-disubstituted 1,2,4-thiadiazoles from ketones, amidines, and sulfur powder under palladium-catalyzed conditions was developed. In this transformation, aromatic ketones act as both the carbon and acyl sources. The reaction provided efficient access to 3-aryl-5-acyl-1,2,4-thiadiazoles from readily available starting materials.
- Subjects
PALLADIUM catalysts; THIADIAZOLES; KETONES; SULFUR; AMIDINES
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 12, p1604
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201700148