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- Title
Cascade Reactions of Unprotected Ketoses with Ketones - A Stereoselective Access to C-Glycosides.
- Authors
Richter, Celin; Krumrey, Michael; Klaue, Kristin; Mahrwald, Rainer
- Abstract
A highly stereoselective de-Bruyn-Ekenstein rearrangement/aldol condensation/intramolecular oxa-Michael cascade reaction of unprotected ketoses with ketones was elaborated. By the utilization of this new and operationally simple methodology an access to β-C-glycosides is given. Extremely matched and mismatched cases were observed by using with natural or unnatural proline in these cascade reactions.
- Subjects
KETOSES; KETONES; STEREOSELECTIVE reactions; GLYCOSIDES; ORGANOCATALYSIS; ALDOL condensation; REARRANGEMENTS (Chemistry)
- Publication
European Journal of Organic Chemistry, 2016, Vol 2016, Issue 31, p5309
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201601058