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- Title
Electrophilic Addition of Allylic Carbocations to 2-Cyclopropylidene-2-arylethanols: A Strategy to 3-Oxabicyclo[3.2.0]heptanes.
- Authors
Meng, Bo; Huang, Xian; Wu, Luling
- Abstract
We have developed an electrophilic addition of allylic carbocations to 2-cyclopropylidene-2-arylethanols constructing carbon-carbon bonds with excellent regio- and stereoselectivities. The reaction affords 3-oxabicyclo[3.2.0]heptanes in moderate to good yields via the electrophilic addition/ring-opening/vinyl group shift/intramolecular cyclization sequence.
- Subjects
ELECTROPHILIC addition reactions; CARBOCATIONS; CARBON-carbon bonds; STEREOSELECTIVE reactions; REGIOSELECTIVITY (Chemistry); RING formation (Chemistry); HEPTANE; VINYL polymers
- Publication
Advanced Synthesis & Catalysis, 2013, Vol 355, Issue 13, p2637
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201201073