We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Probing a Gas/Liquid Acid-Base Reaction by X-ray Photoelectron Spectroscopy.
- Authors
Niedermaier, Inga; Taccardi, Nicola; Wasserscheid, Peter; Maier, Florian; Steinrück, Hans‐Peter
- Abstract
A mechanistic study: In a Brønsted acid/base reaction, gaseous triflic acid (OTfH) transfers its proton to the basic Cl− anion of the ionic liquid [C8C1Im]Cl forming volatile HCl and the IL [C8C1Im][TfO]. This anion exchange reaction is monitored in the near‐surface region quantitatively by X‐ray photoelectron spectroscopy as a function of time (see picture; BE=binding energy).
- Subjects
X-ray photoelectron spectroscopy; ACID-base chemistry research; GAS-liquid interfaces; CHLORIDES; IONIC liquids; BRONSTED acids
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 34, p8904
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201304115