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- Title
Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry.
- Authors
Butovskiy, Mikhail V.; Balázs, Gábor; Bodensteiner, Michael; Peresypkina, Eugenia V.; Virovets, Alexander V.; Sutter, Jörg; Scheer, Manfred
- Abstract
Pentaphosphaferrocene redox chemistry: Unprecedented dianionic and PP coupled and monomeric products are obtained by the reduction of pentaphosphaferrocene with KH or K metal, whereas by oxidation a PP coupled P102+ ligand coordinated to two Cp*Fe units is obtained. The redox behavior clearly distinguishes pentaphosphaferrocene from its organometallic relative, ferrocene.
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 10, p2972
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201209329