We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Twofold Unsymmetrical CH Functionalization of PyrDipSi-Substituted Arenes: A General Method for the Synthesis of Substituted meta-Halophenols.
- Authors
Sarkar, Dhruba; Melkonyan, Ferdinand S.; Gulevich, Anton V.; Gevorgyan, Vladimir
- Abstract
And the world is your oyster…︁ Sequential halogenation/oxygenation reactions of 2‐diisopropylsilylpyrimidine‐substituted arenes provide a general and efficient synthesis of substituted meta‐halophenols from simple aryl iodides (see scheme; Piv=pivaloyl). The products are poised to undergo diverse CC, CN, and CO bond‐forming reactions that enable the transformation of their framework and the introduction of valuable functionalities.
- Subjects
HALOPHENOLS; CHEMICAL reactions; HALOGENATION; DEHALOGENATION; OXYGENATION (Chemistry); AROMATIC compounds
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 41, p10800
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201304884