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- Title
Ring Opening Metathesis Polymerization of a New Monomer Derived from a Nitroso Diels–Alder Reaction.
- Authors
Subnaik, Selesha; Sheridan, Katya; Hobbs, Christopher E.
- Abstract
A nitroso Diels–Alder (NDA) reaction between cyclopentadiene and an in situ generated nitroso compound leads to a new heterocyclic monomer for ring opening metathesis polymerization (ROMP) reactions. This monomer could be polymerized in the presence of Grubbs‐third generation initiator with good control over Mn and decent Ð values. The resulting isoxazolidine‐containing material could undergo further hydrogenation, deprotection, and modification with Dansyl chloride as well as ring opening to provide an amino‐and hydroxyl‐decorated "polyolefin."
- Subjects
DIELS-Alder reaction; MONOMERS; POLYMERIZATION; NITROSO compounds; LEAD compounds; POLYOLEFINS
- Publication
Macromolecular Chemistry & Physics, 2021, Vol 222, Issue 14, p1
- ISSN
1022-1352
- Publication type
Article
- DOI
10.1002/macp.202100098