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- Title
Complex formation in the system monomer-initiator-solvent with polymerization of isoprene in isopropyl alcohol under the influence of hydrogen peroxide.
- Authors
Boiko, V.; Tiurina, T.; Grishchenko, V.
- Abstract
The interactions in two and three component mixtures of isoprene, hydrogen peroxide, and isopropyl alcohol have been studied by H NMR spectroscopy. The groups participating in formation of the complex have been established, and the equilibrium constants have been determined. The results obtained indicate a probable structure of the complex and confirm the possibility of a lighter decomposition of hydrogen peroxide in the ternary complex.
- Subjects
COMPLEX compounds synthesis; MONOMERS; SOLVENTS; POLYMERIZATION; ISOPROPYL alcohol; HYDROGEN peroxide; NUCLEAR magnetic resonance spectroscopy
- Publication
Theoretical & Experimental Chemistry, 2013, Vol 48, Issue 6, p401
- ISSN
0040-5760
- Publication type
Article
- DOI
10.1007/s11237-013-9288-8