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- Title
The photoassociation and photodissociation in laser-assisted collision reaction H + Cl<sup>+</sup>.
- Authors
Niu, Ying‐Yu; Wang, Rong; Su, Qian‐Zhen; Cong, Shu‐Lin
- Abstract
The collision reaction H + Cl+ assisted by the ultra-short laser pulse is investigated using the time-dependent quantum wave packet method. The probability of dissociation depends on the yield ratio of association product HCl+. The greater the laser frequency is, the lower the vibrational level of HCl+ is. With lowering laser frequency, the probabilities of photoassociation and photodissociation increase, and the ratio of products H+ + Cl(2P0) to H(2S) + Cl+(1D) also increases. The kinetic energy spectra of the dissociated fragments at low frequency are wider than those at high frequency. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2008
- Subjects
ATOMS; MOLECULES; WAVE packets; PHOTODISSOCIATION; POTENTIAL energy surfaces; QUANTUM chemistry
- Publication
International Journal of Quantum Chemistry, 2008, Vol 108, Issue 2, p289
- ISSN
0020-7608
- Publication type
Article
- DOI
10.1002/qua.21429