We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
One-Pot Synthesis of a 1,2-Diphospholide by Double C-H Deprotonation.
- Authors
Dixon, Lily S. H.; Matthews, Peter D.; Solomon, Sophia A.; Wright, Dominic S.
- Abstract
The relationship between phosphorus and carbon chemistry has been realized for many years. Phosphorus relatives of classical organic ligands (like cyclopentadienide, Cp-) in which carbon atoms have been substituted for phosphorus atoms are important classes of organometallic ligands, which are relevant to catalysis. Often, however, a limit to applying the phosphorus counterparts is the low-yielding and circuitous nature of their synthesis. A case in point is the 1,2-diphospholide ligand framework, an important analogue of the cyclopentadienyl ligand, which has only been obtained from multistep syntheses. We report in this paper a high-yielding and direct route to this type of framework using a very simple approach. Treatment of MesPHLi (Mes = 2,4,6-trimethylphenyl) with Sb(NMe2)3 generates the 5,7-dimethyl-1,2-benzodiphosphol-1-ide anion ( 1), the first 1,2-diphospholide analogue of indenyl. Structural and NMR spectroscopic investigations suggest that this unique reaction, involving double C-H deprotonation of a CH3 group of the Mes ligand, occurs through the rearrangement of a tetraphospha-1,4-diide anion.
- Subjects
PHOSPHORUS compound synthesis; PROTON transfer reactions; LIGANDS (Chemistry); ANIONS; MOLECULAR structure
- Publication
European Journal of Inorganic Chemistry, 2015, Vol 2015, Issue 12, p2041
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201500177