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- Title
Cover Feature: Mechanistic Insights into the Formation of δ‐Lactones by Cerium‐Catalyzed Aerobic Coupling of β‐Oxoesters with Enol Acetates (Eur. J. Org. Chem. 6/2021).
- Authors
Speldrich, Jean‐Marico; Christoffers, Jens
- Abstract
Cover Feature: Mechanistic Insights into the Formation of -Lactones by Cerium-Catalyzed Aerobic Coupling of -Oxoesters with Enol Acetates (Eur. J. Org. Keywords: Baeyer-Villiger oxidation; Lactones; Reaction mechanism; Synthetic methods EN Baeyer-Villiger oxidation Lactones Reaction mechanism Synthetic methods 860 860 1 02/17/21 20210212 NES 210212 B The Cover Feature b shows the excited cuckoo dashing out of his (radical) clock, because the mechanism of the cerium-catalyzed radical coupling reaction of -oxoesters, enol acetates, and dioxygen was finally elucidated by the introduction of cyclopropyl substituents as radical clocks. Baeyer-Villiger oxidation, Lactones, Reaction mechanism, Synthetic methods.
- Subjects
ENOLS; ACETATES; BAEYER-Villiger rearrangement
- Publication
European Journal of Organic Chemistry, 2021, Vol 2021, Issue 6, p860
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202100062