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- Title
Exploring the Role of Coinage Metalates in Trifluoromethylation: A Combined Experimental and Theoretical Study.
- Authors
Martínez de Salinas, Sara; Mudarra, Ángel L.; Odena, Carlota; Martínez Belmonte, Marta; Benet‐Buchholz, Jordi; Maseras, Feliu; Pérez‐Temprano, Mónica H.
- Abstract
Despite the known nucleophilic nature of [M(CF3)2]− (M=Cu, Ag, Au) complexes, their participation in trifluoromethylation reactions of aryl halides remains unexplored. Here, for the first time, selective access to a [Cu(CF3)2]− species is reported, which is ubiquitous in Cu‐mediated trifluoromethylations, and we rationalize its complex mechanistic scenario as well as its behavior compared to its silver and gold congeners through a combination of experimental and computational approaches.
- Subjects
COINAGE; ARYL halides; GOLD; SILVER
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 40, p9390
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201900496