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- Title
Frontispiece: A Novel Cathode Material for Cathodic Dehalogenation of 1,1-Dibromo Cyclopropane Derivatives.
- Authors
Gütz, Christoph; Selt, Maximilian; Bänziger, Markus; Bucher, Christoph; Römelt, Christina; Hecken, Nadine; Gallou, Fabrice; Galvão, Tomás R.; Waldvogel, Siegfried R.
- Abstract
Pharmaceutical Electrochemistry. The electrochemical dehalogenation represents a powerful and sustainable tool for the synthesis of pharmaceutically relevant cyclopropane building blocks in excellent yield. The key to the conversion is the leaded bronze cathode instead of traditional lead. This novel cathode material is less prone to corrosion and provides highly pure product. Thereby, contamination by heavy metal traces is tremendously reduced. Furthermore, by slightly switching the electrolysis conditions, selective mono ‐ or twofold dehalogenation is achieved. For more details, see the Communication by S. R. Waldvogel and co ‐ workers on page 13878 ff.
- Subjects
CATHODES; CYCLOPENTANE derivatives; DEHALOGENATION
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 40, pn/a
- ISSN
0947-6539
- Publication type
Other
- DOI
10.1002/chem.201584061