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- Title
Zur Deutung der thermodynamischen Daten von Komplexbildungsreaktionen I.
- Authors
Anderegg, G.
- Abstract
The free enthalpy of complex formation, corrected for the involved change of the number of particles, is described as a sum: δ Gta + δ Gtu (= δ G - δ Gm), which permits the separation of the temperature dependent terms. Following Gurney, it is supposed that the temperature dependent free enthalpy δ G ta varies in the same way as the reciprocal of the dielectric constant of the solvent. This model furnishes some relations which permit a correct description of the complex formation in terms of an electrovalent and of a nonelectrovalent interaction.
- Publication
Helvetica Chimica Acta, 1968, Vol 51, Issue 8, p1856
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19680510806