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- Title
A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units.
- Authors
Zhang, Zhong; Zhao, Jun‐Wei; Yang, Guo‐Yu
- Abstract
A trizirconium(IV)-substituted sandwich-type polyoxotungstate, K7.5H6.5[Zr3(µ2-OH)2(µ2-O)(A-α-GeW9O34)(1,4,9-α-P2W15O56)] ·16.5H2O ( 1), was hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy, and single-crystal X-ray diffraction. The structural unit of 1 consists of trilacunary Dawson-type phosphotungstate and trilacunary Keggin-type germanotungstate units that are linked by a trizirconium(IV) cluster.
- Subjects
ZIRCONIUM compounds; POLYOXOMETALATES; POLYOXOTUNGSTATES; HYDROTHERMAL synthesis; SINGLE crystals
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 26, p3244
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201700410