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- Title
Rhodium(I) acetylacetonato complexes containing phosphinoalkynes as catalysts for the hydroboration of vinylarenes.
- Authors
Vogels, Christopher M.; Decken, Andreas; Westcott, Stephen A.
- Abstract
Three novel rhodium(I) acetylacetonato (acac) complexes bearing phosphinoalkynes (Ph2PC≡C-t-Bu, Ph2PC≡CPPh2, and Ph2PC≡CC≡CPPh2) have been prepared and characterized fully. Addition of B2cat3 (cat = 1,2-O2C6H4) to Rh(acac)(Ph2PC≡C-t-Bu)2 (1a) led to zwitterionic Rh(η6-catBcat)(Ph2PC≡C-t-Bu)2 (2a), the first example of this type of compound to contain monodentate phosphine ligands. All new rhodium complexes have been investigated for their ability to catalyse the hydroboration of vinylarenes.
- Subjects
RHODIUM; PLATINUM group; CATALYSTS; HYDROBORATION; ORGANIC chemistry
- Publication
Canadian Journal of Chemistry, 2006, Vol 84, Issue 2, p146
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/V05-242