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- Title
<sup>13</sup>C isotopic labeling to decipher the iron corrosion mechanisms in a carbonated anoxic environment.
- Authors
Lotz, Hélène; Neff, Delphine; Mercier‐Bion, Florence; Bataillon, Christian; Nuns, Nicolas; Dillmann, Philippe
- Abstract
A two‐step corrosion experiment was performed on a ferritic steel (Armco) in a synthetic solution representing the Callovo–Oxfordian at 120°C. After the development of a carbonated corrosion product layer (CPL) during the first 15 days of the experimental step, corrosion front progression was investigated using 13C marked carbonate species during the second 15 days experimental step. CPL was characterized at each step, in terms of morphology (scanning electron microscopy), composition (energy‐dispersive spectroscopy), and structure (µ‐Raman). 13C corrosion product locations were analyzed by time‐of‐flight secondary ion mass spectrometry. Results evidenced that after a step of generalized corrosion, iron corrosion continues locally at the metal/CPL interface. These results suggest that although a protective siderite layer formed on the iron surface after 15 days, a local dissolution of the carbonate layer at the M/CPL interface occurred. A galvanic effect is developed between the bared surface (anode) and the covered one (cathode). This activates iron oxidation. The precipitation of carbonate corrosion products to the metal/CPL interface is possible by the diffusion of 13CO32− ions from the bulk through the siderite layer.
- Subjects
IRON corrosion; SECONDARY ion mass spectrometry; FERRITIC steel; IRON oxidation; ELECTROLYTIC corrosion; SCANNING electron microscopy
- Publication
Materials & Corrosion / Werkstoffe und Korrosion, 2024, Vol 75, Issue 6, p786
- ISSN
0947-5117
- Publication type
Article
- DOI
10.1002/maco.202314203