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- Title
A Facile Synthesis of a Wide Variety of Cationic Ruthenium Hydrido-Arene Complexes of binap (=1,1′-Binaphthalene-2,2′-diylbis(diphenylphosphane)) and MeObiphep (=6,6′-Dimethoxybiphenyl-2,2′-diylbis(diphenylphosphane)).
- Authors
Geldbach, Tilmann J.; Pregosin, Paul S.
- Abstract
A straightforward high-yield synthetic route to the cationic hydrido-arene complexes [RuH( η6-arene)(binap or MeObiphep)](CF3SO3), with a variety of arenes containing both donor and acceptor substituents, is described. 13C-NMR Data for these complexes are reported. Several of these Ru-complexes have been used as transfer-hydrogenation catalysts in the reduction of acetophenone.
- Publication
Helvetica Chimica Acta, 2002, Vol 85, Issue 11, p3937
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/1522-2675(200211)85:11<3937::AID-HLCA3937>3.0.CO;2-X