We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Formation of a Cluster H<sub>2</sub>V<sub>10</sub>O<sub>28</sub><sup>4-</sup> under the Action of Brønsted Acids and Its Catalytic Activity in Oxidation of Alkylbenzenes.
- Authors
Ul’yanova, M. I.; Pervova, M. G.; Slepukhin, P. A.; Aksenova, T. V.; Pestov, A. V.
- Abstract
New method was developed for the preparation of vanadium cluster of the composition {Me2NH2}4* H2V10O28 from vanadyl(IV) acetylacetonate in the presence of 2-hydroxy-2-trifluoromethylchroman-4-one or its synthetic precursor, 2′-hydroxyacetophenone. The structure of the cluster was proved by X-ray diffraction (XRD) analysis. The cluster of decavanadate catalyzes oxidation of toluene and o-xylene creating promising situation for developing new catalytic materials.
- Subjects
BRONSTED acids; CATALYTIC activity; ALKYLBENZENES; HYDROXYACETOPHENONES; ORTHOXYLENE; TOLUENE; OXIDATION
- Publication
Russian Journal of Organic Chemistry, 2018, Vol 54, Issue 5, p687
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428018050020