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- Title
Reactions of diols with dimethyl carbonate in the presence of W(CO) and Co(CO).
- Authors
Khusnutdinov, R.; Shchadneva, N.; Mayakova, Yu.
- Abstract
Dimethoxyalkanes and dimethyl alkanediyl biscarbonates were synthesized by reactions of diols with dimethyl carbonate in the presence of tungsten and cobalt carbonyls. Optimal reactant and catalyst ratios and reaction conditions were found to ensure selective formation of dimethoxyalkanes or dimethyl alkanediyl biscarbonates.
- Subjects
GLYCOLS; ETHANE derivatives; CARBONATE synthesis; CARBONYL compounds; CHEMICAL synthesis; TUNGSTEN compounds synthesis; COBALT compounds synthesis; ALKYLENES
- Publication
Russian Journal of Organic Chemistry, 2014, Vol 50, Issue 7, p948
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428014070057