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- Title
Ultralow-voltage field-ionization discharge on whiskered silicon nanowires for gas-sensing applications.
- Authors
Banan Sadeghian, Ramin; Saif Islam, M.
- Abstract
Several hundred million volts per centimetre of electric-field strength are required to field-ionize gas species. Such fields are produced on sharp metallic tips under a bias of a few kilovolts. Here, we show that field ionization is possible at dramatically lower fields on semiconductor nanomaterials containing surface states, particularly with metal-catalysed whiskers grown on silicon nanowires. The low-voltage field-ionization phenomena observed here cannot be explained solely on the basis of the large field-amplification effect of suspended gold nanoparticles present on the whisker tips. We postulate that field penetration causes upward band-bending at the surface of exposed silicon containing surface states in the vicinity of the catalyst. Band-bending enables the valence electron to tunnel into the surface states at reduced fields. This work provides a basis for development of low-voltage ionization sensors. Although demonstrated on silicon, low-voltage field ionization can be detected on any sharp semiconductor tip containing proper surface states.
- Subjects
IONIZATION of gases; SILICON; NANOWIRES; METALLIC whiskers; ELECTRIC fields; SEMICONDUCTOR nanoparticles; SURFACE chemistry; CONDUCTION electrons
- Publication
Nature Materials, 2011, Vol 10, Issue 2, p135
- ISSN
1476-1122
- Publication type
Article
- DOI
10.1038/nmat2944