We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Delicate and Fast Photochemical Surface Modification of 2D Photoresponsive Organosilicon Metal–Organic Frameworks.
- Authors
Yuan, Baoling; Gou, Gaozhang; Fan, Tao; Liu, Mingxian; Ma, Yunsheng; Matsuda, Ryotaro; Li, Liangchun
- Abstract
Photoresponsive arylsilanes have been fascinating molecules for decades because of their unique photophysical characteristics and surface chemistry. Here we report the synthesis and fabrication of a crystalline two‐dimensional trisilyl metal–organic framework (TSiMOF) orderly installed with the classical photoresponsive hexamethyltrisilane groups on the surface. Irradiated by UV light under air in minutes the fluorescence of the TSiMOF is turned on simultaneously with an intriguing surface transformation from superhydrophobic to hydrophilic. Thus, multifarious luminescent and hydrophilic patterns including logos, characters and Quick Response codes, etc. with good resolution are readily generated on the facilely fabricated TSiMOF film. The mechanism of this transformation is revealed by control experiments that the superficial trimethylsilyl groups suffering photochemical oxidation have been converted to hydroxyl groups.
- Subjects
METAL-organic frameworks; TWO-dimensional bar codes; SURFACE chemistry; HYDROXYL group
- Publication
Angewandte Chemie, 2022, Vol 134, Issue 28, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202204568