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- Title
An Unusual and Facile Synthetic Route to Alumoles.
- Authors
Li, Jiancheng; Wu, Peng; Jiang, Wenjun; Li, Bin; Wang, Binju; Zhu, Hongping; Roesky, Herbert W.
- Abstract
Reaction of the aluminum dialkynyl LAl(CCR)2 (L=N,N‐chelate ligand and R=organic group) with B(C6F5)3 proceeds through an intermediate with Al⋅⋅⋅η2‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐containing heterocycles. The synthetic process is described, and the characterization of compounds and computational calculations were carried out. Furthermore, alumoles 2 and 4 exhibit an aggregation‐induced emission (AIE) of the bright yellow fluorescence.
- Subjects
ALUMINUM; FLUORESCENCE; PROCEEDS; HETEROCYCLIC compounds
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 25, p10113
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202000899