We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Peripheral Amplification of Multi‐Resonance Induced Thermally Activated Delayed Fluorescence for Highly Efficient OLEDs.
- Authors
Liang, Xiao; Yan, Zhi‐Ping; Han, Hua‐Bo; Wu, Zheng‐Guang; Zheng, You‐Xuan; Meng, Hong; Zuo, Jing‐Lin; Huang, Wei
- Abstract
Abstract: Multi‐resonance induced by boron and nitrogen atoms in opposite resonance positions endows a thermally activated delayed fluorescence (MR‐TADF) emitter with a strikingly small full width at half maximum of only 26 nm and excellent photoluminescence quantum yield of up to 97.48 %. The introduction of a carbazole unit in the para position of the B‐substituted phenyl‐ring can significantly boost up the resonance effect without compromising the color fidelity, subsequently enhancing the performances of the corresponding pure blue TADF‐OLED, with an outstanding external quantum efficiency (EQE) up to 32.1 % and low efficiency roll‐off, making it one of the best TADF‐OLEDs in the blue region to date. Furthermore, utilizing this material as host for a yellow phosphorescent emitter, the device also shows a significantly reduced turn‐on voltage of 3.2 V and an EQEmax of 22.2 %.
- Subjects
ORGANIC light emitting diodes; FLUORESCENCE; NITROGEN; QUANTUM chemistry; CHEMICAL yield; QUANTUM efficiency
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 35, p11486
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201806323