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- Title
Photochemische Reaktionen. 116. Mitteilung [1]. Notiz zur <sup>1</sup>γ, δ*-induzierten Photospaltung von γ, δ-Epoxy-eucarvon.
- Authors
Tsutsumi, Kentaro; Wolf, Hans Richard
- Abstract
π, π*-Induced Photocleavage of γ, δ-Epoxy-eucarvone. On 1π, π*-excitation 1 undergoes cleavage of the C, C-oxirane bond ( 1 → c) and isomerizes to the bicyclic dihydrofurane compound 5. In addition, 1 shows photocleavage of the C (γ), O-oxirane bond ( 1 → d) and gives the isomers 2, 3, 6, 7 and 8. Furthermore, the cyclohexenone 9 and the cyclohexene-1, 4-dione 10 are formed presumably via an intermediate 13, which could also arise from d. Besides these products the compounds 11 and 12 are obtained, which are photoproducts of 2.
- Publication
Helvetica Chimica Acta, 1980, Vol 63, Issue 8, p2370
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19800630828