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- Title
Efficient Synthesis of Optically Pure Mono- and Binuclear Macrocyclic Polylactones from Castor Oil and Sebacic Acid.
- Authors
Ishmuratov, G. Yu.; Medvedeva, N. I.; Saitov, K. M.; Yakovleva, M. P.; Nazarov, I. S.; Tolstikov, A. G.
- Abstract
An efficient synthesis of optically pure macrocyclic mono- and binuclear polylactones has been proposed. The synthesis is based on the condensation of natural triol, castor oil, with sebacoyl dichloride in 1 : 1 or 1 : 2 ratios in boiling carbon tetrachloride in the presence of triethylamine and N,N-dimethylaminopyridine as a catalyst.
- Subjects
CASTOR oil; ETHYLAMINES; ACIDS; TRIETHYLAMINE; CONDENSATION reactions; CARBON tetrachloride
- Publication
Doklady Chemistry, 2023, Vol 513, Issue 1, p315
- ISSN
0012-5008
- Publication type
Article
- DOI
10.1134/S0012500823601031