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- Title
Transition Metal‐free Phosphorylation of Vinyl Azides: A Convenient Synthesis of β‐Ketophosphine Oxides.
- Authors
Jang, Jihoon; Kim, Dae Young
- Abstract
To demonstrate the practicality of the transition metal-free phosphorylation of vinyl azides, the gram-scale reaction was conducted under optimized reaction conditions. In conclusion, we have developed a practical synthetic method for the preparation of -ketophosphine oxide derivatives from the reaction between vinyl azide derivatives and diphenylphosphine oxides under transition metal-free conditions. (c) M. Zhou, M. Chen, Y. Zhou, K. Yang, J. Su, J. Du, Q. Song, Org. 14 For a selection of our recent works on C-H activation, see:(a) Y. K. Kang, S. M. Kim, D. Y. Kim, J. Am. Chem. Soc. 2010, 132, 11847.
- Subjects
AZIDATION; OXIDE synthesis; AZIDES; PHOSPHORYLATION; NORMAL-phase chromatography; ORGANIC synthesis; TRANSITION metal oxides; BENZENE derivatives
- Publication
Bulletin of the Korean Chemical Society, 2020, Vol 41, Issue 3, p370
- ISSN
0253-2964
- Publication type
Article
- DOI
10.1002/bkcs.11964