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- Title
Metal Amides as the Simplest Acid/Base Catalysts for Stereoselective Carbon-Carbon Bond-Forming Reactions.
- Authors
Yamashita, Yasuhiro; Kobayashi, Shū
- Abstract
In this paper, new possibilities for metal amides are described. Although typical metal amides are recognized as strong stoichiometric bases for deprotonation of inert or less acidic hydrogen atoms, transition-metal amides, namely silver and copper amides, show interesting abilities as one of the simplest acid/base catalysts in stereoselective carbon-carbon bond-forming reactions.
- Subjects
AMIDES; ACID-base chemistry; STEREOSELECTIVE reactions; CARBON-carbon bonds; PROTON transfer reactions; HYDROGEN atom
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 29, p9420
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201300908