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- Title
Sequence-Dependent Self-Assembly of Chiral Polyimides.
- Authors
Yan, Jijun; Kang, Chuanqing; Bian, Zheng; Jin, Rizhe; Ma, Xiaoye; Du, Zhijun; Yao, Haibo; Gao, Lianxun
- Abstract
Sequence-defined chiral polyimides comprising identical asymmetric diamine monomers arranged in different directions along the main chain were designed and prepared. These new sequence-defined polymers exhibit sequence-dependent self-assembly behaviors and responses to ibuprofen enantiomers, as revealed by their chiroptical spectra and gelation properties. For the first time, the self-assembly of polymers and their interactions with guest molecules have been successfully controlled by means of the directional arrangement of the monomers in their polymer backbones.
- Subjects
POLYIMIDES; DIAMINES; MONOMERS; POLYMERS; IBUPROFEN; ENANTIOMERS
- Publication
Chemistry - An Asian Journal, 2017, Vol 12, Issue 8, p841
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.201700284