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- Title
Water-Stabilized Three- and Four-Atom Palladium Clusters as Highly Active Catalytic Species in Ligand-Free CC Cross-Coupling Reactions.
- Authors
Leyva‐Pérez, Antonio; Oliver‐Meseguer, Judit; Rubio‐Marqués, Paula; Corma, Avelino
- Abstract
Elite cliques: Palladium clusters with three and four atoms were found to be the catalytically active species for ligand‐free palladium‐catalyzed CC bond‐forming reactions (see picture). These palladium cluster species could be stabilized in water and stored for long periods of time for use on demand with no loss of activity. High yields of products and turnover frequencies (TOFs) of up to 105 h−1 were observed.
- Subjects
PALLADIUM; COUPLING reactions (Chemistry); CHEMICAL reactions; HECK reaction; NANOPARTICLES; LIGANDS (Chemistry)
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 44, p11554
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201303188