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- Title
Acenaphthoimidazolylidene‐ligated chiral oxazoline palladacycles: synthesis, structure, and application in intramolecular α‐arylation of amides towards 3,3′‐disubstituted oxindoles.
- Authors
Yang, Hanxiao; Wang, Kun; Fang, Weiwei
- Abstract
A general catalytic protocol for the Pd‐catalyzed intramolecular arylations of N‐(2‐halogenoaryl) amides in eco‐friendly medium was successfully developed by using rationally designed acenaphthoimidazolylidene‐ligated chiral oxazoline palladacycles. Under the optimal reaction condition, a broad scope of substrates with various functional groups were well tolerated, leading to desired 3,3′‐disubstituted oxindoles in excellent yields (up to 98% yield).
- Subjects
OXAZOLINE synthesis; OXINDOLES; AMIDES; OXAZOLINE; FUNCTIONAL groups; PALLADACYCLES; ARYLATION
- Publication
Asian Journal of Organic Chemistry, 2023, Vol 12, Issue 5, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202300120