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Title
A Novel Synthetic Procedure for Stereoblock Poly(propylene) with a Living Polymerization System (Supporting information for this article is available on the journal's homepage at http://www.mrc-journal.de or from the author which gives details about experimental procedures, <sup>13</sup>C NMR spectra, and DSC profiles of syndiotactic, atactic, stereoblock PPs, and blend polymers obtained.)