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- Title
Comparison of Ligands in Palladium-catalyzed Electrochemical Allyl 4-Pyridinylation.
- Authors
Wei-Jie Ding; Chun-Hui Yang; Zhong-Tao Feng; Shi-Rong Lu; Xu Cheng
- Abstract
4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radicalpolar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated.
- Subjects
PALLADIUM catalysts; PYRIDINE; LIGANDS (Chemistry); CHEMICAL reactions; ELECTROCHEMISTRY
- Publication
Journal of Electrochemistry, 2024, Vol 30, Issue 5, p1
- ISSN
1006-3471
- Publication type
Article
- DOI
10.61558/2993-074X.3438