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- Title
Dioxoiodane Compounds as Versatile Sources for Iodine(I) Chemistry.
- Authors
Muñiz, Kilian; García, Belén; Martínez, Claudio; Piccinelli, Alessandro
- Abstract
The general synthesis, isolation and characterization of electrophilic iodine reagents of the general formula R4N[I(O2CAr)2] is reported. These compounds are air- and moisture-stable iodine(I) reagents, which were characterized including X-ray analysis. They represent conceptually new iodine(I) reagents with anions as stabilizers. These compounds display the expected performance as electrophilic reagents upon interaction with electron-rich substrates. The performance of these compounds in a total of 47 different reactions of vicinal iodooxygenation of alkenes is studied and some key features on the reagents are revealed.
- Subjects
IODINE compounds synthesis; CHEMICAL reagents; ELECTROPHILES; ANIONS; OXYGENATION (Chemistry); ALKENES
- Publication
Chemistry - A European Journal, 2017, Vol 23, Issue 7, p1539
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201603801