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- Title
Field-Induced Slow Relaxation in a Dinuclear Dysprosium(III) Complex Based on 3-Methoxycinnamic Acid.
- Authors
Khalfaoui, Ouafa; Beghidja, Adel; Long, Jérôme; Beghidja, Chahrazed; Guari, Yannick; Larionova, Joulia
- Abstract
We report the synthesis, structure, and magnetic properties of a new dinuclear dysprosium(III) complex based on a 3-methoxycinnamate ligand. The centrosymmetric complex exhibits a field-induced SMM behavior. In contrast to the previously reported lanthanide-based systems with cinnamate derivatives that relax through a combination of Raman and direct processes, an Orbach process is also involved in highlighting the role of the structural organization over the spin-lattice relaxations.
- Subjects
METAL complexes; DYSPROSIUM compounds; CHEMICAL relaxation; CINNAMIC acid; LIGANDS (Chemistry); RARE earth metals
- Publication
Inorganics, 2018, Vol 6, Issue 1, p35
- ISSN
2304-6740
- Publication type
Article
- DOI
10.3390/inorganics6010035