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- Title
Acyl Radicals from Aromatic Carboxylic Acids by Means of Visible- Light Photoredox Catalysis.
- Authors
Bergonzini, Giulia; Cassani, Carlo; Wallentin, Carl‐Johan
- Abstract
Simple and abundant carboxylic acids have been used as acyl radical precursor by means of visible-light photoredox catalysis. By the transient generation of a reactive anhydride intermediate, this redox-neutral approach offers a mild and rapid entry to high-value heterocyclic compounds without the need of UV irradiation, high temperature, high CO pressure, tin reagents, or peroxides.
- Subjects
ACYL radicals; PHOTOCATALYSIS; HETEROCYCLIC compounds synthesis; CHEMICAL synthesis; CARBOXYLIC acids; VISIBLE spectra; INTERMEDIATES (Chemistry)
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 47, p14272
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201506432