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- Title
6,6′-Di-(8″-quinoline)-2,2′-bipyridine Cobalt(II) Complex.
- Authors
Li, Yuwei; Tong, Lianpeng
- Abstract
This short note describes the synthesis of a novel compound, 6,6′-di-(8″-quinoline)-2,2′-bypyridine (2), that bears a bipyridyl backbone and quinoline donors. Compound 2 coordinates with a cobalt(II) ion in a tetradentate manner and affords the complex [CoII(2)(TfO)2], whose molecular structure has been identified by single crystal X-ray diffraction crystallographic analysis. The coordination features of 2 were compared with those of 2,2′:6′,2″:6″,2‴-quaterpyridine (qtpy, 1), a well-studied tetradentate polypyridine ligand. Compound 2 presents a new example of tetradentate chelators for 3d metal ions.
- Subjects
COBALT; COBALT compounds; MOLECULAR structure; SINGLE crystals; METAL ions; BIPYRIDINE
- Publication
Molbank, 2023, Vol 2023, Issue 2, pM1615
- ISSN
1422-8599
- Publication type
Article
- DOI
10.3390/M1615