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Selective Late-Stage Hydrodefluorination of Trifluoromethylarenes: A Facile Access to Difluoromethylarenes.
- Published in:
- European Journal of Organic Chemistry, 2017, v. 2017, n. 16, p. 2322, doi. 10.1002/ejoc.201700396
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- Article
From C<sub>1</sub> to C<sub>3</sub>: Copper‐Catalyzed gem‐Bis(trifluoromethyl)olefination of α‐Diazo Esters with TMSCF<sub>3</sub>.
- Published in:
- Angewandte Chemie International Edition, 2020, v. 59, n. 22, p. 8507, doi. 10.1002/anie.202002409
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- Article
A General Protocol for C−H Difluoromethylation of Carbon Acids with TMSCF<sub>2</sub>Br.
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- Angewandte Chemie International Edition, 2019, v. 58, n. 19, p. 6405, doi. 10.1002/anie.201900763
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- Article
From C<sub>1</sub> to C<sub>2</sub>: TMSCF<sub>3</sub> as a Precursor for Pentafluoroethylation.
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- Angewandte Chemie International Edition, 2018, v. 57, n. 40, p. 13211, doi. 10.1002/anie.201807873
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- Article
Hypervalent Iodine(III)‐Catalyzed Balz–Schiemann Fluorination under Mild Conditions.
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- Angewandte Chemie International Edition, 2018, v. 57, n. 31, p. 9896, doi. 10.1002/anie.201802466
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- Article
Efficient Difluoromethylation of Alcohols Using TMSCF<sub>2</sub>Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions.
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- Angewandte Chemie International Edition, 2017, v. 56, n. 12, p. 3206, doi. 10.1002/anie.201611823
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- Article
Stereoselective Carbonyl Olefination with Fluorosulfoximines: Facile Access to Z or E Terminal Monofluoroalkenes.
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- Angewandte Chemie International Edition, 2017, v. 56, n. 2, p. 619, doi. 10.1002/anie.201610127
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- Article
Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me<sub>3</sub>SiCF<sub>2</sub>H.
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- Angewandte Chemie International Edition, 2016, v. 55, n. 41, p. 12632, doi. 10.1002/anie.201605280
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- Article
Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis.
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- Angewandte Chemie International Edition, 2016, v. 55, n. 8, p. 2743, doi. 10.1002/anie.201510533
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- Article
Inside Cover: Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis (Angew. Chem. Int. Ed. 8/2016).
- Published in:
- Angewandte Chemie International Edition, 2016, v. 55, n. 8, p. 2604, doi. 10.1002/anie.201600459
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- Article
N‐Heteroaromatic Fluoroalkylation through Ligand Coupling Reaction of Sulfones.
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- Angewandte Chemie, 2024, v. 136, n. 19, p. 1, doi. 10.1002/ange.202401091
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- Article
Controllable Double Difluoromethylene Insertions into S−Cu Bonds: (Arylthio)tetrafluoroethylation of Aryl Iodides with TMSCF<sub>2</sub>Br.
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- Angewandte Chemie, 2024, v. 136, n. 14, p. 1, doi. 10.1002/ange.202400839
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- Article
Transition‐Metal‐Free Controllable Single and Double Difluoromethylene Formal Insertions into C−H Bonds of Aldehydes with TMSCF<sub>2</sub>Br.
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- Angewandte Chemie, 2023, v. 135, n. 7, p. 1, doi. 10.1002/ange.202217088
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- Article
TMSCF<sub>2</sub>Br‐Enabled Fluorination–Aminocarbonylation of Aldehydes: Modular Access to α‐Fluoroamides.
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- Angewandte Chemie, 2022, v. 134, n. 8, p. 1, doi. 10.1002/ange.202115467
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- Article
Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro‐tert‐butylation with 1,1‐Dibromo‐2,2‐bis(trifluoromethyl)ethylene (DBBF) and CsF.
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- Angewandte Chemie, 2021, v. 133, n. 52, p. 27524, doi. 10.1002/ange.202113727
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- Article
Iron‐Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential.
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- Angewandte Chemie, 2021, v. 133, n. 24, p. 13709, doi. 10.1002/ange.202102597
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- Publication type:
- Article
From C<sub>1</sub> to C<sub>3</sub>: Copper‐Catalyzed gem‐Bis(trifluoromethyl)olefination of α‐Diazo Esters with TMSCF<sub>3</sub>.
- Published in:
- Angewandte Chemie, 2020, v. 132, n. 22, p. 8585, doi. 10.1002/ange.202002409
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- Publication type:
- Article
A General Protocol for C−H Difluoromethylation of Carbon Acids with TMSCF<sub>2</sub>Br.
- Published in:
- Angewandte Chemie, 2019, v. 131, n. 19, p. 6471, doi. 10.1002/ange.201900763
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- Publication type:
- Article
Nucleophilic Fluoroalkylation of α, β-Unsaturated Carbonyl Compounds with α-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts.
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- Helvetica Chimica Acta, 2012, v. 95, n. 10, p. 2043, doi. 10.1002/hlca.201200445
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- Article
Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF<sub>2</sub>CH<sub>3</sub>).
- Published in:
- Chemistry - An Asian Journal, 2016, v. 11, n. 12, p. 1789, doi. 10.1002/asia.201600577
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- Article
Pentafluoroethylation of Arenediazonium Tetrafluoroborates Using On‐Site Generated Tetrafluoroethylene.
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- Chinese Journal of Chemistry, 2019, v. 37, n. 11, p. 1131, doi. 10.1002/cjoc.201900268
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- Article
Fluoro‐Hydroxylation of gem‐Difluoroalkenes: Synthesis of <sup>18</sup>O‐labeled α‐CF<sub>3</sub> Alcohols.
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- Chinese Journal of Chemistry, 2018, v. 36, n. 12, p. 1202, doi. 10.1002/cjoc.201800426
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- Article
Copper-Mediated Di- and Monofluoromethanesulfonylation of Arenediazonium Tetrafluoroborates: Probing the Fluorine Effect.
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- Chinese Journal of Chemistry, 2018, v. 36, n. 3, p. 206, doi. 10.1002/cjoc.201700748
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- Article
Pentafluoroethylbenziodoxole (BIX-C<sub>2</sub>F<sub>5</sub>): A Shelf-Stable Reagent for Pentafluoroethylation of β-Ketoesters and Arylboronic Acids.
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- Chinese Journal of Chemistry, 2016, v. 34, n. 7, p. 662, doi. 10.1002/cjoc.201600097
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- Article
Copper-Mediated Deuterotrifluoromethylation of α?Diazo Esters.
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- Chinese Journal of Chemistry, 2016, v. 34, n. 5, p. 469, doi. 10.1002/cjoc.201600004
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- Article
Cover Picture: Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF<sub>2</sub>H: Facile Entry into gem-Difluoroalkenes (Chin. J. Chem. 8/2014).
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- Chinese Journal of Chemistry, 2014, v. 32, n. 8, p. 657, doi. 10.1002/cjoc.201490017
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- Article
Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF<sub>2</sub>H: Facile Entry into gem-Difluoroalkenes.
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- Chinese Journal of Chemistry, 2014, v. 32, n. 8, p. 703, doi. 10.1002/cjoc.201400403
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- Article
Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane.
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- Chinese Journal of Chemistry, 2013, v. 31, n. 7, p. 878, doi. 10.1002/cjoc.201300365
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- Article
Stereoselective Nucleophilic Fluoromethylation of Aryl Ketones: Dynamic Kinetic Resolution of Chiral α-Fluoro Carbanions.
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- Angewandte Chemie International Edition, 2014, v. 53, n. 3, p. 775, doi. 10.1002/anie.201308484
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- Article
Synthesis of gem-Difluorocyclopropa(e)nes and O -, S -, N -, and P-Difluoromethylated Compounds with TMSCF<sub>2</sub>Br.
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- Angewandte Chemie International Edition, 2013, v. 52, n. 47, p. 12390, doi. 10.1002/anie.201306703
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- Article
Difluoro(sulfinato)methylation of N-Sulfinyl Imines Facilitated by 2-Pyridyl Sulfone: Stereoselective Synthesis of Difluorinated β-Amino Sulfonic Acids and Peptidosulfonamides.
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- Angewandte Chemie International Edition, 2013, v. 52, n. 41, p. 10835, doi. 10.1002/anie.201304395
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- Article
On the Nature of CH⋅⋅⋅FC Interactions in Hindered CF<sub>3</sub>C(sp<sup>3</sup>) Bond Rotations.
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- Angewandte Chemie International Edition, 2011, v. 50, n. 49, p. 11761, doi. 10.1002/anie.201105288
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- Article
From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation.
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- Angewandte Chemie International Edition, 2011, v. 50, n. 11, p. 2559, doi. 10.1002/anie.201007594
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- Publication type:
- Article
1,6-Nucleophilic Di- and Trifluoromethylation of para -Quinone Methides with Me 3 SiCF 2 H/Me 3 SiCF 3 Facilitated by CsF/18-Crown-6.
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- Molecules, 2024, v. 29, n. 12, p. 2905, doi. 10.3390/molecules29122905
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- Article
Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral α-Difluoromethylamines from Ketimines.
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- Molecules, 2022, v. 27, n. 20, p. 7076, doi. 10.3390/molecules27207076
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- Article
SulfoxFluor-enabled deoxyazidation of alcohols with NaN<sub>3</sub>.
- Published in:
- Nature Communications, 2022, v. 13, n. 1, p. 1, doi. 10.1038/s41467-022-30132-x
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- Article
Transition‐Metal‐Free Electrophilic Fluoroalkanesulfinylation of Electron‐Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)−S and S=O Bond Cleavage.
- Published in:
- Advanced Synthesis & Catalysis, 2019, v. 361, n. 24, p. 5528, doi. 10.1002/adsc.201900959
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- Article
A Remarkably Efficient Fluoroalkylation of Cyclic Sulfates and Sulfamidates with PhSO<sub>2</sub>CF<sub>2</sub>H: Facile Entry into β-Difluoromethylated or β-Difluoromethylenated Alcohols and Amines.
- Published in:
- Angewandte Chemie International Edition, 2007, v. 46, n. 5, p. 786, doi. 10.1002/anie.200603983
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- Article
China's flourishing synthetic organofluorine chemistry: innovations in the new millennium.
- Published in:
- National Science Review, 2017, v. 4, n. 3, p. 303, doi. 10.1093/nsr/nwx058
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- Article
N‐Heteroaromatic Fluoroalkylation through Ligand Coupling Reaction of Sulfones.
- Published in:
- Angewandte Chemie International Edition, 2024, v. 63, n. 19, p. 1, doi. 10.1002/anie.202401091
- By:
- Publication type:
- Article
Controllable Double Difluoromethylene Insertions into S−Cu Bonds: (Arylthio)tetrafluoroethylation of Aryl Iodides with TMSCF<sub>2</sub>Br.
- Published in:
- Angewandte Chemie International Edition, 2024, v. 63, n. 14, p. 1, doi. 10.1002/anie.202400839
- By:
- Publication type:
- Article
Transition‐Metal‐Free Controllable Single and Double Difluoromethylene Formal Insertions into C−H Bonds of Aldehydes with TMSCF<sub>2</sub>Br.
- Published in:
- Angewandte Chemie International Edition, 2023, v. 62, n. 7, p. 1, doi. 10.1002/anie.202217088
- By:
- Publication type:
- Article
TMSCF<sub>2</sub>Br‐Enabled Fluorination–Aminocarbonylation of Aldehydes: Modular Access to α‐Fluoroamides.
- Published in:
- Angewandte Chemie International Edition, 2022, v. 61, n. 8, p. 1, doi. 10.1002/anie.202115467
- By:
- Publication type:
- Article
Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro‐tert‐butylation with 1,1‐Dibromo‐2,2‐bis(trifluoromethyl)ethylene (DBBF) and CsF.
- Published in:
- Angewandte Chemie International Edition, 2021, v. 60, n. 52, p. 27318, doi. 10.1002/anie.202113727
- By:
- Publication type:
- Article
Iron‐Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential.
- Published in:
- Angewandte Chemie International Edition, 2021, v. 60, n. 24, p. 13597, doi. 10.1002/anie.202102597
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- Publication type:
- Article
S‐(Trifluoromethyl)Benzothioate (TFBT): A KF‐Based Reagent for Nucleophilic Trifluoromethylthiolation.
- Published in:
- Chemistry - A European Journal, 2022, v. 28, n. 13, p. 1, doi. 10.1002/chem.202104395
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- Article
Front Cover: S‐(Trifluoromethyl)Benzothioate (TFBT): A KF‐Based Reagent for Nucleophilic Trifluoromethylthiolation (Chem. Eur. J. 13/2022).
- Published in:
- Chemistry - A European Journal, 2022, v. 28, n. 13, p. 1, doi. 10.1002/chem.202200482
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- Publication type:
- Article
S‐(Trifluoromethyl)Benzothioate (TFBT): A KF‐Based Reagent for Nucleophilic Trifluoromethylthiolation.
- Published in:
- Chemistry - A European Journal, 2022, v. 28, n. 13, p. 1, doi. 10.1002/chem.202104395
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- Publication type:
- Article
Difluorocarbene‐Induced Ring‐Opening Difluoromethylation‐Halogenation of Cyclic (Thio)Ethers with TMSCF<sub>2</sub>X (X=Br, Cl)**.
- Published in:
- Chemistry - A European Journal, 2021, v. 27, n. 71, p. 17773, doi. 10.1002/chem.202103428
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- Article
Frontispiece: Rapid Deoxyfluorination of Alcohols with N‐Tosyl‐4‐chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature.
- Published in:
- Chemistry - A European Journal, 2019, v. 25, n. 30, p. N.PAG, doi. 10.1002/chem.201983063
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- Article