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- Title
Attempted synthesis of 2-oxo-N-phenyltetracyclo[7.2.1.0<sup>2,6</sup>.0<sup>5,11</sup>]-dodecane-9,10-dicarboximide by intramolecular ɑ-ketocarbene insertion into an unactivated C-H bond.
- Authors
Camps, Pelayo; Fernández, José A.; Vázquez, Santiago; Font-Bardia, Mercè; Solans, Xavier
- Abstract
The diastereoselective preparation of 4ɑ-(diazomethylcarbonyl)-N-phenyltricyclo[5.2.1.02,6]-decane-2β,6β-dicarboximide and attempts to transform this compound into a derivative containing the tetracyclo[7.2.1.02,6.05,11]dodecane skeleton are described.
- Subjects
DICARBOXIMIDES; ORGANIC synthesis; CARBENES; ACTIVATION (Chemistry); CARBON-hydrogen bonds; CHEMICAL derivatives; DIAZOKETONES
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2011, p358
- ISSN
1551-7004
- Publication type
Article