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- Title
Synthesis and Spectral and Coordination Properties of meso-Tetraarylporphyrins.
- Authors
Ivanova, Yu. B.; Semeikin, A. S.; Pukhovskaya, S. G.; Mamardashvili, N. Zh.
- Abstract
5,10,15,20-Tetrakis(3,5-dibromophenyl)porphyrin and 5,10,15,20-tetrakis(3-bromo-4-methoxy-phenyl)porphyrin have been synthesized, and their complexing properties with respect to Pd2+ ion in acetonitrile at 308–328 K have been studied by spectrophotometry. The synthesized compounds were characterized by UV-Vis, 1H NMR, and mass spectra. The effect of substitueras in the meso-phenyl rings of the ligands on their spectral and coordination properties was estimated in comparison to 5,10,15,20-tetraphenylporphyrin.
- Subjects
MASS spectrometry; METALLOPORPHYRINS; PORPHYRINS; DIPYRROMETHANES; DIPYRRINS
- Publication
Russian Journal of Organic Chemistry, 2019, Vol 55, Issue 12, p1878
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S107042801912011X