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- Title
Asymmetric Hydrophosphonylation of Aldehydes using a Cinchona–Diaminomethylenemalononitrile Organocatalyst.
- Authors
Hirashima, Shin ‐ ichi; Arai, Ryoga; Nakashima, Kosuke; Kawai, Nobuaki; Kondo, Junko; Koseki, Yuji; Miura, Tsuyoshi
- Abstract
For the asymmetric hydrophosphonylation of aldehydes, an efficient organocatalytic approach with a diaminomethylenemalononitrilebased hydrogen-bonding donor catalyst is presented. The catalyst induces high yields and excellent enantioselectivities (up to 98% yield, 96% ee).
- Subjects
ASYMMETRIC synthesis; ALDEHYDE synthesis; ORGANOCATALYSIS; NITRILE synthesis; CINCHONA; HYDROGEN bonding
- Publication
Advanced Synthesis & Catalysis, 2015, Vol 357, Issue 18, p3863
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201500816