We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study.
- Authors
Hidalgo, Nereida; Moreno, Juan José; García‐Rubio, Inés; Campos, Jesús
- Abstract
The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed‐shell states. The reactivity of their metalloradical species is though remarkable, albeit yet poorly understood and with limited mechanistic investigations available. In this work we report the synthesis and characterization of two mononuclear IrII species, including the first dinitrogen adduct. These compounds activate dihydrogen at a dissimilar rate, in the latter case several orders of magnitude faster than its IrI precursor. A combined experimental/computational investigation to ascertain the mechanism of this transformation in IrII compounds is reported.
- Subjects
IRIDIUM; TRANSITION metals; ORGANOMETALLIC chemistry
- Publication
Angewandte Chemie, 2022, Vol 134, Issue 35, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202206831