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- Title
Syntheses, characterization and properties of copper, silver and palladium complexes with oxazoline-containing ligands.
- Authors
Hu, Tao; Zhou, Wei; Kuai, Hai-Wei; Zhang, Hai-Ming
- Abstract
The reactions of copper, silver and palladium salts with the homochiral ligands 3,3′-bis[(S,S)-4-isopropyl-2-oxazolyl]-4-chloro-2,2′-bipyridine (L1), 3,3′-bis[(S,S)-4-benzyl-2-oxazolyl]-4-chloro-2,2′-bipyridine (L2) and 2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L3) yield three new chiral complexes: [Cu(L1)Br2] (1), [Ag(L2)(CH3CN)]·(BF4)·(CH3OH)0.17·(H2O)0.08 (2) and [Pd(L3)Cl2]·(CH3COCH3)0.5 (3), which have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. The complexes 1–3 display discrete mononuclear structures. Non-linear optical properties of complexes 1–3 were investigated.
- Subjects
COPPER; SONOGASHIRA reaction; PALLADIUM compounds; LIGANDS (Chemistry); SILVER; SILVER salts; THERMOGRAVIMETRY
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2023, Vol 78, Issue 9/10, p519
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2023-0056