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- Title
Design strategy of enediynes and enyne-allenes.
- Authors
Maretina, I.
- Abstract
The review summarizes synthetic approaches to enediynes and enyne-allenes that are responsible for a Bergman and Myers-Saito cycloaromatizations resulting in the formation of benzene, β-substituted naphthalene, and acene derivatives. Cycloaromatization paths leading to fulvene and indene systems in the presence of radical and ionic initiators, as well as of metal catalysts, are discussed. Practical importance of the syntheses is noted.
- Subjects
ENEDIYNES; ANTINEOPLASTIC antibiotics; BENZENE; POLYCYCLIC aromatic hydrocarbons; METAL catalysts; NAPHTHALENE
- Publication
Russian Journal of General Chemistry, 2008, Vol 78, Issue 2, p223
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363208020126