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- Title
Isokinetic Parameters of Thermal Degradation of Powder of [Cd(N-Boc-gly)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sub>n</sub>.
- Authors
Begoviæ, N.; Vasiæ, M. M.; Grkoviæ, A.; Blagojeviæ, V. A.; Miniæ, D. M.
- Abstract
The coordination polymer [Cd(N-Boc-gly)2(H2O)2]n undergoes thermally induced degradation in temperature region between 60 and 900°C. Kinetic parameters were determined for dehydration (63-123°C) and further degradation processes (123-461°C) using different isoconversional and non-isoconversional methods. Due to appearance of kinetic "compensation effect", isokinetic temperatures were determined for individual degradation processes and correlated with resonant vibrational frequencies ascribed to Cd-OH2 coordination bond, Cd-O (O from N-Boc-glyH ligand) coordination bond and C-O covalent bond.
- Subjects
CHEMICAL decomposition; THERMAL analysis; HYDROGEN peroxide; COORDINATION polymers; RANDOM vibration; RESONANCE
- Publication
Science of Sintering, 2014, Vol 46, Issue 3, p323
- ISSN
0350-820X
- Publication type
Article
- DOI
10.2298/SOS1403323B